Tag Archives: palladium

Pd-catalyzed Mizoroki-Heck reaction of [Ph2SR][OTf] with alkenes

Fluoroalkyl(diaryl)sulfonium salts are conventional but useful synthetic reagents in the preparation of functional molecules. S-Trifluoromethyl(diaryl)sulfonium salts, known as the Yagupolskii-Umemoto reagents ([Ar2SCF3]X (X = OTf, BF4)) and initially exploited as electrophilic +CF3 transfer sources for a variety