Tag Archives: Carbene C-H insertion

Chemoselective Intramolecular carbene C-H insertions of 2-diazo-2-sulfamoylacetamides

The transition-metal-catalyzed intramolecularly aliphatic and aromatic C-H insertions of diazo amides provide useful and important transformations to efficiently synthesize nitrogen-containing heterocycles with the new generated C-C bond. The reactivity of different diazoamide derivatives has been well studied